Reductive coupling and protonation leading to diboron corroles with a B-H-B bridge.
نویسندگان
چکیده
The reaction of PhBCl(2) with free base triarylcorroles results in a spontaneous reduction to give diboron corrole complexes (PhBHBPh)(Cor) in which a proton has been captured to form a bridging B-H-B group encapsulated within the corrole ligand. The proposed mechanism is supported by the reaction of PhBF(2) with H(3)Cor to give (PhBF)(BPh)(Cor) in which no reduction has occurred.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 17 شماره
صفحات -
تاریخ انتشار 2010